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Measurements made using specially designed, more elaborate apparatus and more astute sampling-handling techniques have yielded radiocarbon ages for anthracite greater than 70,000 radiocarbon years, the sensitivity limit of this equipment. Continuous series of tree-ring dated wood samples have been obtained for roughly the past 10,000 years which give the approximate correct radiocarbon age, demonstrating the general validity of the conventional radiocarbon dating technique.
Several long tree-ring chronologies have been constructed specifically for use in calibrating the radiocarbon time scale.
I am not aware of any authentic research which supports this claim.
Comparison of ancient, historically dated artifacts (from Egypt, for example) with their radiocarbon dates has revealed that radiocarbon years and calendar years are not the same even for the last 5,000 calendar years.It is not correct to state or imply from this evidence that the radiocarbon dating technique is thus shown to be generally invalid.The problem with freshwater clams arises because these organisms derive the carbon atoms which they use to build their shells from the water in their environment.Other radiometric dating methods such as potassium-argon or rubidium-strontium are used for such purposes by those who believe that the earth is billions of years old.Radiocarbon is not suitable for this purpose because it is only applicable: a) on a time scale of thousands of years and b) to remains of once-living organisms (with minor exceptions, from which rocks are excluded).
This gives the clam shell an artificially old radiocarbon age.